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EN
ČeštinaEnglish

Generating Palladium Nanoclusters Inside Very Lipophilic Gel-Type Functional Resins: Preliminary Catalytic Tests in the Hydrogenation of 2-Ethyl-Anthraquinone to 2-Ethylanthrahydroquinone.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F03%3A27030032" target="_blank" >RIV/67985858:_____/03:27030032 - isvavai.cz</a>

  • Result on the web

    —

  • DOI - Digital Object Identifier

    —

Alternative languages

  • Result language

    angličtina

  • Original language name

    Generating Palladium Nanoclusters Inside Very Lipophilic Gel-Type Functional Resins: Preliminary Catalytic Tests in the Hydrogenation of 2-Ethyl-Anthraquinone to 2-Ethylanthrahydroquinone.

  • Original language description

    Four lipophilic polystyrene-methacryloylethylensulfonic acid-divinylbenzene gel-type resins, with 2 and 4% cross-linking degree, are synthesized and used as supports for 'atomic' dispersion of Pd(II) finalized to the preparation of resins-supported palladium metal catalysts. Properly performed reduction of Pd(II) to Pd(0) achieves homogeneous dispersion of ca. 3 nm metal nanoclusters inside the supports particles in the more cross-linked resin. Resulting resin-supported palladium catalysts are efficientand moderately chemoselective in the hydrogenation of 2-ethylanthraquinone to 2-ethylanthrahydroquinone.

  • Czech name

    —

  • Czech description

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Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

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Result continuities

  • Project

    —

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Catalysis A: Chemical

  • ISSN

    1381-1169

  • e-ISSN

    —

  • Volume of the periodical

    194

  • Issue of the periodical within the volume

    1-2

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    9

  • Pages from-to

    273-281

  • UT code for WoS article

    —

  • EID of the result in the Scopus database

    —

Similar results(10)

Controllable deposition of dispersed Pd nanoparticles on ZnO for Suzuki-Miyaura cross-coupling reactionsPreparation of Pd/Al2O3 catalysts using microemulsion systemHighly Chemoselective Hydrogenation of 2-Ethylanthraquinone to 2-Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed inside Highly Lipophilic Functional Resins.