Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to 2-Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed inside Highly Lipophilic Functional Resins.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F02%3A27020093" target="_blank" >RIV/67985858:_____/02:27020093 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to 2-Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed inside Highly Lipophilic Functional Resins.
Original language description
Most of hydrogen peroxide is currently produced via the selective hydrogenation of 2-ethylanthraquinone (EAQ) to 2-ethylanthrahydroquinone (EAHQ), followed by its reaction with dioxygen that produces hydrogen peroxide and regenerates 2-ethylanthraquinone. We have developed novel catalysts for this process, based on palladium supported on very lipophilic functional resins. Upon playing with the structure of the polymer backbone and with the nature of the reaction medium, we have succeeded in promoting achemoselectivity to EAHQ slightly but definitely superior to that provided by a commonly employed commercial catalyst under identical conditions, while maintaining comparable levels of catalytic activity. This finding demonstrates the potential of variations of the lipophilic/hydrophilic character of the support as a tool for the improvement of the chemoselectivity of resin-based metal catalysts.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CI - Industrial chemistry and chemical engineering
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GA104%2F99%2F0125" target="_blank" >GA104/99/0125: Hypersulfonated ion exchanger catalysts</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Chemistry European Journal
ISSN
0947-6539
e-ISSN
—
Volume of the periodical
8
Issue of the periodical within the volume
13
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
2962-2967
UT code for WoS article
—
EID of the result in the Scopus database
—