Laser-Induced Gas-Phase Pyrolysis of Dimethyl Selenium: Chemical Deposition of Selenium and Poly(selenoformaldehyde)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F04%3A00104768" target="_blank" >RIV/67985858:_____/04:00104768 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Laser-Induced Gas-Phase Pyrolysis of Dimethyl Selenium: Chemical Deposition of Selenium and Poly(selenoformaldehyde)
Original language description
Continuous-wave and pulsed CO2 laser-induced and SF6-photosensitized pyrolysis of dimethyl selenium yields methane, ethene and ethane as three major gaseous products and affords chemical vapour deposition of a composite of elemental selenium and a polymer assigned from FTIR and XP spectra as poly(selenoformaldehyde). The mechanism of the pyrolysis is discussed in terms of radical paths and transient formation of selenoformaldehyde
Czech name
Laserově iniciovaná pyrolýza plynného dimetylselenu: chemická deposice selenu a poly(selenoformaldehydu)
Czech description
Pyrolýza plynného dimetyl selenu iniciovaná kontinuálním a pulsním CO2 laserem a fotosenzibilovaná hexafluoridem síry vede k tvorbě metanu, etanu a etylenu (třem hlavním produktům) a dovoluje chemickou deposici selenu a polymeru, jehož struktura byla interpretována pomocí IČ a XP spekter jako poly(selenoformaldehyd). Mechanismus pyrolýzy je diskutován v termínech radikálových reakcí a přechodné tvorby selenoformaldehydu
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Analytical and Applied Pyrolysis
ISSN
0165-2370
e-ISSN
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Volume of the periodical
71
Issue of the periodical within the volume
2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
10
Pages from-to
635-644
UT code for WoS article
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EID of the result in the Scopus database
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