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On the Role of the Reference System in Perturbation Theory: An Augmented van der Waals Theory of Simple Fluids

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F09%3A00324980" target="_blank" >RIV/67985858:_____/09:00324980 - isvavai.cz</a>

  • Alternative codes found

    RIV/44555601:13440/09:00004859

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    On the Role of the Reference System in Perturbation Theory: An Augmented van der Waals Theory of Simple Fluids

  • Original language description

    In this study, we show that the inclusion of a short-range part of the total attractive interaction into a reference system allows a natural extension of the traditional first-order perturbation theory of simple fluids to practically all thermodynamic states. This theory is applied to the thermodynamic functions and the liquid-vapor coexistence curve of the Lennard-Jones-like medium range Yukawa fluid and to the Sutherland fluid. Comparison with computer simulation data and the second-order Barker-Henderson perturbation theory is discussed.

  • Czech name

    Úloha referenčního systému v poruchové teorii: Zobecněná van der Waalsova rovnice jednoduchých kapalin

  • Czech description

    Je ukázáno, že zahrnutí krátkodosahové části celkového potenciálu do referenčního systému umožňuje rozšířit použitelnost poruchového rozvoje 1. řádu na celou oblast termodynamických podmínek. Teorie je aplikována na Lennard-Jonesovu-Yukawovu tekutinu Sutherlandovu tekutinu. Výsledek je porovnán s teorií Barkera-Hendersona.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/IAA400720710" target="_blank" >IAA400720710: Determination of the phase and state behaviour of fluids and fluid mixtures for processes at superambient conditions: molecular-based theory and experiment</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Fluid Phase Equilibria

  • ISSN

    0378-3812

  • e-ISSN

  • Volume of the periodical

    279

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

    000265373400001

  • EID of the result in the Scopus database