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Sedimentation of a Two-Dimensional Colloidal Mixture Exhibiting Liquid-Liquid and Gas-Liquid Phase Separation: A Dynamical Density Functional Theory Study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F13%3A00425957" target="_blank" >RIV/67985858:_____/13:00425957 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22340/13:43895557

  • Result on the web

    <a href="http://dx.doi.org/10.1063/1.4823768" target="_blank" >http://dx.doi.org/10.1063/1.4823768</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1063/1.4823768" target="_blank" >10.1063/1.4823768</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Sedimentation of a Two-Dimensional Colloidal Mixture Exhibiting Liquid-Liquid and Gas-Liquid Phase Separation: A Dynamical Density Functional Theory Study

  • Original language description

    We present dynamical density functional theory results for the time evolution of the density distribution of a sedimenting model two-dimensional binary mixture of colloids. The interplay between the bulk phase behaviour of the mixture, its interfacial properties at the confining walls, and the gravitational field gives rise to a rich variety of equilibrium and non-equilibrium morphologies. In the fluid state, the system exhibits both liquid-liquid and gas-liquid phase separation. As the system sediments, the phase separation significantly affects the dynamics and we explore situations where the final state is a coexistence of up to three different phases. Solving the dynamical equations in two-dimensions, we find that in certain situations the final density profiles of the two species have a symmetry that is different from that of the external potentials, which is perhaps surprising, given the statistical mechanics origin of the theory. The paper concludes with a discussion on this.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA13-09914S" target="_blank" >GA13-09914S: A controlling of diffusion processes in pores with varying permeability</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical Physics

  • ISSN

    0021-9606

  • e-ISSN

  • Volume of the periodical

    139

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

  • UT code for WoS article

    000325780800047

  • EID of the result in the Scopus database