Cobalt(I) and Cobalt(III) Cyclopentadienyl Complexes with New Silicon-branched Fluorous Tags
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F14%3A00424138" target="_blank" >RIV/67985858:_____/14:00424138 - isvavai.cz</a>
Alternative codes found
RIV/44555601:13440/14:43885730
Result on the web
<a href="http://dx.doi.org/10.1016/j.jfluchem.2013.12.010" target="_blank" >http://dx.doi.org/10.1016/j.jfluchem.2013.12.010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jfluchem.2013.12.010" target="_blank" >10.1016/j.jfluchem.2013.12.010</a>
Alternative languages
Result language
angličtina
Original language name
Cobalt(I) and Cobalt(III) Cyclopentadienyl Complexes with New Silicon-branched Fluorous Tags
Original language description
Two new fluorous tags based on omega-[tris(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silyl]alkyl substituents (alkyl = ethyl, propyl) were synthesized from 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl iodide as the fluorine-containing component. Cyclopentadienes (the mixtures of 1- and 2-substituted isomers) which bore the tags were prepared, cyclopentadienylcobalt(I) dicarbonyl complexes were subsequently obtained from the reactions of the cyclopentadienes with dicobalt octacarbonyl. Oxidative additions of 1-iodoperfluoroalkanes on the cobalt(I) complexes provided cobalt(III) complexes with one of their four ponytails bonded directly to the metal and with a stereocenter at the metal.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP106%2F12%2F1372" target="_blank" >GAP106/12/1372: Highly fluorous cyclopentadienes for applications in catalysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Fluorine Chemistry
ISSN
0022-1139
e-ISSN
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Volume of the periodical
159
Issue of the periodical within the volume
MAR 2014
Country of publishing house
CH - SWITZERLAND
Number of pages
6
Pages from-to
15-20
UT code for WoS article
000332141900003
EID of the result in the Scopus database
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