Computer Study of Chromatographic Separation Process: A Monte Carlo Study of H-Shaped and Linear Homopolymers in Good Solvent.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00458098" target="_blank" >RIV/67985858:_____/16:00458098 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/16:10325148 RIV/44555601:13440/16:43887488
Result on the web
<a href="http://dx.doi.org/10.1021/acs.macromol.5b02327" target="_blank" >http://dx.doi.org/10.1021/acs.macromol.5b02327</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.macromol.5b02327" target="_blank" >10.1021/acs.macromol.5b02327</a>
Alternative languages
Result language
angličtina
Original language name
Computer Study of Chromatographic Separation Process: A Monte Carlo Study of H-Shaped and Linear Homopolymers in Good Solvent.
Original language description
The partitioning, of linear (L) and H-shaped polymers between bulk solvent and narrow pores with inert and attractive Walls and the conformational behavior of chains in pores was studied by Monte Carlo simulations. The polymer chains were modeled as self-avoiding walks in a good solvent. The concentration profiles in the pores, partition coefficients KH and KD and various structural characteristics were calculated as, functions of pore size and interaction parameter epsilon, ranging from a to -0.26. K-H is, higher than K-L in pores with nonattractive walls, but the difference decreases with increasing vertical bar epsilon vertical bar. Both partition coefficients equal for epsilon ca. -0.2, and later their sequence inverts. epsilon depends only slightly on chain architecture and chain length. The results are important from the experimental point of view because they show that the improperly chosen experimental conditions Can deteriorate SEC analysis of branched samples.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Macromolecules
ISSN
0024-9297
e-ISSN
—
Volume of the periodical
49
Issue of the periodical within the volume
3
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
1093-1102
UT code for WoS article
000370113300038
EID of the result in the Scopus database
2-s2.0-84957975609