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Effect of Preparation Method on Catalytic Properties of Co-Mn-Al Mixed Oxides for N2O Decomposition.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00467588" target="_blank" >RIV/67985858:_____/16:00467588 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989100:27730/16:86099784 RIV/61989100:27710/16:86099784 RIV/61989100:27360/16:86099784

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.molcata.2016.10.014" target="_blank" >http://dx.doi.org/10.1016/j.molcata.2016.10.014</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.molcata.2016.10.014" target="_blank" >10.1016/j.molcata.2016.10.014</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of Preparation Method on Catalytic Properties of Co-Mn-Al Mixed Oxides for N2O Decomposition.

  • Original language description

    Co-Mn-Al mixed oxides (Co:Mn:Al molar ratio of 4:1:1) were prepared by three different methods (i) calcination of hydrotalcite-like precursors (Co-Mn-Al-HT-ex), (ii) calcination of corresponding nitrates (Co-Mn-Al-nitr) and (iii) calcination of the product of mechanochemical reaction of Co, Mn, Al nitrates with NH4HCO3 (Co-Mn-Al-carb). Different conditions of synthesis led to the formation of spinel-like phase with different structural properties leading to different catalytic activity.N2O conversions decreased with decreasing specific surface area in order Co-Mn-Al-carb > Co-Mn-Al-HT-ex > Co-Mn-Al-nitr. Highest catalyst activity was determined by the lowest bond strength of active site oxygen while specific surface area and amount of active sites per unit surface were not decisive parameters for activities order.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CI - Industrial chemistry and chemical engineering

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Molecular Catalysis A-Chemical

  • ISSN

    1381-1169

  • e-ISSN

  • Volume of the periodical

    425

  • Issue of the periodical within the volume

    DEC 15

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    11

  • Pages from-to

    237-247

  • UT code for WoS article

    000390634100027

  • EID of the result in the Scopus database

    2-s2.0-84992206945