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Modified Single-Walled Carbon Nanotube Membranes for the Elimination of Antibiotics from Water.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F21%3A00545698" target="_blank" >RIV/67985858:_____/21:00545698 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/21:43922164 RIV/60461373:22340/21:43922164 RIV/00216208:11310/21:10432581

  • Result on the web

    <a href="https://www.mdpi.com/2077-0375/11/9/720" target="_blank" >https://www.mdpi.com/2077-0375/11/9/720</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/membranes11090720" target="_blank" >10.3390/membranes11090720</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Modified Single-Walled Carbon Nanotube Membranes for the Elimination of Antibiotics from Water.

  • Original language description

    The hydrophilic and hydrophobic single-walled carbon nanotube membranes were prepared and progressively applied in sorption, filtration, and pertraction experiments with the aim of eliminating three antibiotics—tetracycline, sulfamethoxazole, and trimethoprim—as a single pollutant or as a mixture. The addition of SiO2 to the single-walled carbon nanotubes allowed a transparent study of the influence of porosity on the separation processes. The mild oxidation, increasing hydrophilicity, and reactivity of the single-walled carbon nanotube membranes with the pollutants were suitable for the filtration and sorption process, while non-oxidized materials with a hydrophobic layer were more appropriate for pertraction. The total pore volume increased with an increasing amount of SiO2 (from 743 to 1218 mm3/g) in the hydrophilic membranes. The hydrophobic layer completely covered the carbon nanotubes and SiO2 nanoparticles and provided significantly different membrane surface interactions with the antibiotics. Single-walled carbon nanotubes adsorbed the initial amount of antibiotics in less than 5 h. A time of 2.3 s was sufficient for the filtration of 98.8% of sulfamethoxazole, 95.5% of trimethoprim, and 87.0% of tetracycline. The thicker membranes demonstrate a higher adsorption capacity. However, the pertraction was slower than filtration, leading to total elimination of antibiotics (e.g., 3 days for tetracycline). The diffusion coefficient of the antibiotics varies between 0.7–2.7 × 10−10, depending on the addition of SiO2 in perfect agreement with the findings of the textural analysis and scanning electron microscopy observations. Similar to filtration, tetracycline is retained by the membranes more than sulfamethoxazole and trimethoprim.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    <a href="/en/project/GJ19-08153Y" target="_blank" >GJ19-08153Y: Elimination of pharmaceutical drugs and endocrine disruptors from water by membrane processes</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Membranes

  • ISSN

    2077-0375

  • e-ISSN

    2077-0375

  • Volume of the periodical

    11

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    29

  • Pages from-to

    720

  • UT code for WoS article

    000700715700001

  • EID of the result in the Scopus database

    2-s2.0-85115863952