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Polyacrylamide hydrogels prepared by varying water content during polymerization: Material characterization, reswelling ability, and aging resistance.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F22%3A00551964" target="_blank" >RIV/67985858:_____/22:00551964 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22340/22:43925438

  • Result on the web

    <a href="http://hdl.handle.net/11104/0327160" target="_blank" >http://hdl.handle.net/11104/0327160</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/pen.25895" target="_blank" >10.1002/pen.25895</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Polyacrylamide hydrogels prepared by varying water content during polymerization: Material characterization, reswelling ability, and aging resistance.

  • Original language description

    As easily fabricated, polyacrylamide (PAAm) hydrogels are widely used, especially in medicine. Material properties of these crosslinked polymers are usually tuned by varying monomer/crosslinker ratio during polymerization. However, the properties of resulting hydrogels are affected by an all-in composition of the reaction mixture. As the influence of water/monomer ratio has not been systematically studied yet, the objective of this study is to provide a comprehensive investigation of this way of hydrogel preparation together with a careful examination of resulting materials. The samples of PAAm hydrogels prepared with controlled contents of water in the reaction mixture vary in achieved swelling ratios (from 5 to 25) and rigidities (Young's modulus from 300 to 5 kPa). These material properties remain practically the same even if the hydrogels are dried and reswelled again. Performed long-time testing suggests that the PAAm hydrogels can be stored either in wet or dry state, however, to avoid possible degradation by polymer hydrolysis, they should be placed in darkness and stored at no more than room temperature. The prepared hydrogels swell more in NaCl solutions than in water. As this swelling/shrinking behavior is reversible and independent of hydrogel history, it could be applied for remote control of hydrogel properties.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer Engineering and Science

  • ISSN

    0032-3888

  • e-ISSN

    1548-2634

  • Volume of the periodical

    62

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    16

  • Pages from-to

    901-916

  • UT code for WoS article

    000743282100001

  • EID of the result in the Scopus database

    2-s2.0-85122758788