Polyacrylamide hydrogel-based nanocomposites containing graphene, kaolin or laponite: physico-mechanical characterization and adsorption properties.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F23%3A00565551" target="_blank" >RIV/67985858:_____/23:00565551 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0337072" target="_blank" >https://hdl.handle.net/11104/0337072</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.mtcomm.2022.105150" target="_blank" >10.1016/j.mtcomm.2022.105150</a>
Alternative languages
Result language
angličtina
Original language name
Polyacrylamide hydrogel-based nanocomposites containing graphene, kaolin or laponite: physico-mechanical characterization and adsorption properties.
Original language description
Polyacrylamide (PAAm) hydrogel-based nanocomposites containing graphene, kaolin or laponite were prepared and tested as possible adsorbents for organic dyes. The morphology of basic hydrogels was controlled by varying the content of water in the reaction mixture and the composition of final adsorbents was modified by changing the type and amount of the additive. The impact of hydrogel morphology and applied additives on the physico-mechanical properties of prepared nanocomposites was investigated. Concerning morphology, the higher water content (i.e. larger pores) brings about the less rigid hydrogel or nanocomposite. Concerning additives, the addition of graphene or kaolin makes the nanocomposites less rigid, whereas the addition of laponite more rigid than the original PAAm hydrogels. The prepared kaolin and laponite nanocomposites swell in water less than the original hydrogels, the graphene nanocomposites do not exhibit an obvious trend. Both, the hydrogels and all their nanocomposites, swell more in aqueous NaCl solutions than in water. The adsorption properties of prepared nanocomposites toward six organic dyes was then systematically studied. Comparing to the original hydrogels, the adsorption capacity of nanocomposites varies with the type of additive: notably increases for laponite, slightly increases for graphene, and surprisingly decreases for kaolin nanocomposites. Concerning hydrogel morphology, the medium size of pores seems to be the most advantageous. The laponite nanocomposites are found to be efficient adsorbents for cationic dyes, especially those containing phenyl groups. In this case, the desorption of cationic dyes from the adsorbents can be efficiently done by using acid media.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20402 - Chemical process engineering
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Materials Today Communications
ISSN
2352-4928
e-ISSN
2352-4928
Volume of the periodical
34
Issue of the periodical within the volume
March 2023
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
12
Pages from-to
105150
UT code for WoS article
000991216400001
EID of the result in the Scopus database
2-s2.0-85144619825