Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F22%3A00556494" target="_blank" >RIV/67985858:_____/22:00556494 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/22:73615675 RIV/00216224:14310/22:00125868
Result on the web
<a href="http://hdl.handle.net/11104/0330711" target="_blank" >http://hdl.handle.net/11104/0330711</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.jelechem.2022.116261" target="_blank" >10.1016/j.jelechem.2022.116261</a>

Result language
angličtina
Original language name
Cyclopentenedione-based ascorbate-rejecting permselective layers prepared by electropolymerization.
Original language description
This work focuses on the preparation and optimization of organic functional layers based on 4-cyclopentene-1,3-dione. Hybrid molecules composed of 4-cyclopentene-1,3-dione anchored to a polymerizable moiety based either on pyrrole or methoxybenzene derivatives were synthesized and used for the preparation of thin films by electropolymerization. It is shown that the cyclopentenedione-containing films suppress the ascorbate (negatively charged) electrochemical response when deposited on glassy carbon electrodes, while the response connected to dopamine (positively charged) electrooxidation remains unaffected or is only slightly suppressed. The ascorbate-dopamine selectivity was studied in detail by voltammetry with stationary and rotating disk electrodes.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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