Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F14%3A00428338" target="_blank" >RIV/68081707:_____/14:00428338 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/bmc.3091" target="_blank" >http://dx.doi.org/10.1002/bmc.3091</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/bmc.3091" target="_blank" >10.1002/bmc.3091</a>
Alternative languages
Result language
angličtina
Original language name
Chiral separability of boron cluster species studied by screening approaches utilizing polysaccharide-based chiral stationary phases
Original language description
In this study, the screening steps of chiral separation strategies with polysaccharide-based chiral stationary phases were applied on boron cluster compounds in normal-phase liquid chromatography (NPLC) and polar organic solvents chromatography (POSC). Since the screening steps were initially developed to analyze organic compounds, their applicability for boron clusters was investigated. Overall, the screening steps in NPLC were applicable for the separation of zwitterions, while for anions mostly no elution was observed. A hypothesis for the latter behavior is precipitation of anions in the nonpolar mobile phases. Ten out of 11 compounds could be partially or baseline separated on the NPLC screening systems. In POSC, all zwitterions were separated onat least one of the screening systems, with an overall lower retention as in NPLC. Anions were detected but not separated in the majority of the experiments. Also their retention on the chiral stationary phases was very limited.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BO - Biophysics
OECD FORD branch
—
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Biomedical Chromatography
ISSN
0269-3879
e-ISSN
—
Volume of the periodical
28
Issue of the periodical within the volume
5
Country of publishing house
GB - UNITED KINGDOM
Number of pages
14
Pages from-to
694-707
UT code for WoS article
000334197400016
EID of the result in the Scopus database
—