[(eta(6)-p-cymene)Ru(H2O)(3)](2+) binding capability of aminohydroxamates - A solution and solid state study

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F16%3A00461986" target="_blank" >RIV/68081707:_____/16:00461986 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/16:33161168

Result on the web

<a href="http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032" target="_blank" >http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jinorgbio.2016.02.032" target="_blank" >10.1016/j.jinorgbio.2016.02.032</a>

Result language

angličtina

Original language name

[(eta(6)-p-cymene)Ru(H2O)(3)](2+) binding capability of aminohydroxamates - A solution and solid state study

Original language description

Complex forming capabilities of [(eta(6)-p-cymene)Ru(H2O)(3)](2+) with aminohydroxamates (2-amino-N-hydroxyacetamide (alpha-alahaH), 3-amino-N-hydroxypropanamide (beta-alahaH) and 4-amino-N-hydroxybutanamide (gamma-abhaH)) having the primary amino group in different chelatable position to the hydroxamic function were studied by pH-potentiometry, NMR and MS methods. Formation of stable [O,O] and mixed [O,O][N,N] chelated mono- and dinuclear species is detected in partially slow with alpha-alahaH and beta-alahaH or in fast processes with gamma-abhaH and the formation constants of the complexes present in aqueous solution are reported. Synthesis, spectral (NMR, IR) and ESI mass spectrometric characterization of novel dinuclear alpha-alaninehydroximato complexes containing the half-sandwich type Ru(II) core is described. The crystal and molecular structure of [{(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Br]Br center dot H2O (1) and [(eta(6)-p-cymene)Ru)(2)(mu(2)-alpha-alahaH(-1))(H2O)Cl]BF4 center dot H2O (2) was determined by single crystal X-ray diffraction method.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BO - Biophysics

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Inorganic Biochemistry

ISSN

0162-0134

e-ISSN

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Volume of the periodical

160

Issue of the periodical within the volume

JUL2016

Country of publishing house

US - UNITED STATES

Number of pages

10

Pages from-to

236-245

UT code for WoS article

000378965200027

EID of the result in the Scopus database

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