Electrochemical reduction and oxidation of eight unnatural 2 '-deoxynucleosides at a pyrolytic graphite electrode
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F20%3A00536121" target="_blank" >RIV/68081707:_____/20:00536121 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14740/20:00118306
Result on the web
<a href="https://www.sciencedirect.com/science/article/pii/S0013468620316030?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0013468620316030?via%3Dihub</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.electacta.2020.137210" target="_blank" >10.1016/j.electacta.2020.137210</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical reduction and oxidation of eight unnatural 2 '-deoxynucleosides at a pyrolytic graphite electrode
Original language description
Recently we showed the reduction and oxidation of six natural 2'-deoxynucleosides in the presence of the ambient oxygen using the very broad potential window of a pyrolytic graphite electrode (PGE). Using the same procedure, 2'-deoxynucleoside analogs (dNs) that are parts of an artificially expanded genetic information system (AEGIS) were analyzed. Seven of the eight tested AEGIS dNs provided specific signals (voltammetric redox peaks). These signals, described here for the first time, will be used in future work to analyze DNA built from expanded genetic alphabets, helping to further develop AEGIS technology and its applications. Comparison of the electrochemical behavior of unnatural dNs with the previously documented behaviors of natural dNs also provides insights into the mechanisms of their respective redox processes. (C) 2020 Elsevier Ltd. All rights reserved.
Czech name
—
Czech description
—
Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10405 - Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrochimica acta
ISSN
0013-4686
e-ISSN
—
Volume of the periodical
362
Issue of the periodical within the volume
2020
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
137210
UT code for WoS article
000582869700067
EID of the result in the Scopus database
2-s2.0-85092252648