Theory of electrophoretic focusing on aninverse electromigration dispersion profile
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081715%3A_____%2F20%3A00524029" target="_blank" >RIV/68081715:_____/20:00524029 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0308343" target="_blank" >http://hdl.handle.net/11104/0308343</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elps.201900229" target="_blank" >10.1002/elps.201900229</a>
Alternative languages
Result language
angličtina
Original language name
Theory of electrophoretic focusing on aninverse electromigration dispersion profile
Original language description
Electrophoretic focusing on an inverse electromigration dispersion (EMD) profile is basedon a principle different from those of other electrophoretic separation methods. It hasalready proved its applicability in analytical practice by offering competitive separationperformance and sensitivity and specific selectivity. It can be classified as an intermedi-ate between field-driven and equilibrium gradient methods and is therefore interestingfrom the viewpoint of theory of separation methods. This work presents a comprehensivetheoretical description of electrophoretic focusing on an inverse EMD profile compris-ing properties of the electrolyte system, formed gradients, and focused analyte zones. Theseparation properties are described in terms of resolution and peak capacity and their de-pendence on system and analyte properties is discussed from the viewpoint of how thecounteracting phenomena of electromigration and dispersion are affected by electric cur-rent, voltage, and hydrodynamic and electroosmotic flow. The overall performance of thepresent method is shown to be comparable with other electrophoretic separation methodslike zone electrophoresis or isoelectric focusing.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
<a href="/en/project/GA18-13135S" target="_blank" >GA18-13135S: Application of capillary electrophoresis in dried blood spots analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Electrophoresis
ISSN
0173-0835
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
7-8
Country of publishing house
DE - GERMANY
Number of pages
10
Pages from-to
471-480
UT code for WoS article
000490359900001
EID of the result in the Scopus database
2-s2.0-85073931643