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Effect of Zr+4 doping on characteristics and sonocatalytic activity of TiO2/carbon nanotubes composite catalyst for degradation of chlorpyrifos

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F19%3A00505424" target="_blank" >RIV/68081723:_____/19:00505424 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/19:10399597

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S002236971832691X?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S002236971832691X?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jpcs.2019.01.018" target="_blank" >10.1016/j.jpcs.2019.01.018</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of Zr+4 doping on characteristics and sonocatalytic activity of TiO2/carbon nanotubes composite catalyst for degradation of chlorpyrifos

  • Original language description

    Nanotitania/carbon nanotubes composites were prepared using the sol-gel method with different nanotitania:carbon nanotubes ratios. The composite sample was modified with zirconium cation (IV). The prepared com-posites were characterized with different techniques using thermogravimetric analysis (TGA), nitrogen ad-sorption, transmission electron microscopy (TEM), X-ray diffraction (XRD), energy dispersive X-ray (EDX),diffuse reflectance spectroscopy (DRS) and Fourier transform infrared spectroscopy (FTIR). Sonocatalytic de-gradation efficiency of the prepared sonocatalysts was tested for sonocatalytic degradation of chlorpyrifos atdifferent application conditions such as the effect of chlorpyrifos concentration, temperature, catalyst dosage,ultrasonic power and the presence of radiation light. Zirconium modified nanotitania/carbon nanotubes com-posite (ZCT10) shows the maximum sonocatalytic activity (91.5% after 60 min) and obeyed pseudo-first orderkinetic models. The optimum degradation efficiency was also confirmed at 2.0 g/L as catalyst dosage and in-crease with both of application temperature and ultrasonic power. The presence of radiation light can alsoenhance the activity of sonocatalysts. Catalyst reusability experiments showed that catalysts are well reusable fordegradation of chlorpyrifos by the sonocatalytic process.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/LQ1601" target="_blank" >LQ1601: CEITEC 2020</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physics and Chemistry of Solids

  • ISSN

    0022-3697

  • e-ISSN

  • Volume of the periodical

    129

  • Issue of the periodical within the volume

    JUN

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    180-187

  • UT code for WoS article

    000466250300022

  • EID of the result in the Scopus database

    2-s2.0-85060206501