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Synthesis and spectral characterization of mercury(II) complexes with the bidentate Schiff base ligand N,N'-bis(2,3-dimethoxybenzylidene)-1,2-diaminoethane: the crystal structures of [Hg((23-MeO-ba)2en)I2] and [Hg((23-MeO-ba)2en)Br2]

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F11%3A00365633" target="_blank" >RIV/68378271:_____/11:00365633 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.poly.2011.08.024" target="_blank" >http://dx.doi.org/10.1016/j.poly.2011.08.024</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.poly.2011.08.024" target="_blank" >10.1016/j.poly.2011.08.024</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and spectral characterization of mercury(II) complexes with the bidentate Schiff base ligand N,N'-bis(2,3-dimethoxybenzylidene)-1,2-diaminoethane: the crystal structures of [Hg((23-MeO-ba)2en)I2] and [Hg((23-MeO-ba)2en)Br2]

  • Original language description

    Three mercury(II) complexes, [Hg((23-MeO-ba)2en)X2] (X = I (1), Br (2) and Cl(3)), and the ligand (23-MeOba)2en ((23-MeO-ba)2en = N,N0-bis(2,3-dimethoxybenzylidene)-1,2-diaminoethane) have been synthesized and characterized by elemental analyses, FT-IR and 1H NMR spectroscopy. The crystal structures of 1 and 2 were determined by X-ray. The metal-to ligand ratio was found to be 1:1. The mercury(II) center in 1 and 2 has a distorted tetrahedral geometry. The Schiff base ligand (23-MeO-ba)2en acts as a chelating ligand, coordinating via the two nitrogen atoms to the Hg(II) atom, and it adop! ts an E,E conformation. In complex 1 an inter-molecular hydrogen bond C-H...O was found, while in complex 2 inter- and intra-molecular C-H...X (X = O and Br) hydrogenwere found.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP204%2F11%2F0809" target="_blank" >GAP204/11/0809: Absorption, beam homogeneity and varying irradiated volume corrections in multidomain bulk and thin film samples.</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polyhedron

  • ISSN

    0277-5387

  • e-ISSN

  • Volume of the periodical

    30

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    5

  • Pages from-to

    2790-2794

  • UT code for WoS article

    000296996500005

  • EID of the result in the Scopus database