Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2]
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00391678" target="_blank" >RIV/68378271:_____/13:00391678 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1134/S1070328412100077" target="_blank" >http://dx.doi.org/10.1134/S1070328412100077</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S1070328412100077" target="_blank" >10.1134/S1070328412100077</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, spectral characterization, and crystal structure of mononuclear mercury(II) complex [Hg((3,4-MeO-Bza)2En)I2]
Original language description
Mercury(II) complex, [Hg((3,4-MeO-Bza)2En)I2] , where (3,4-MeO-Bza)2En = N,N'-bis(3,4-dimethoxybenzaldehyde)ethylenediimine, has been synthesized from the reaction of HgI2 with (3,4-Me-Bza)2En in methanol as solvent at 50°C. It was characterized by elemental analysis (CHN), 1H-NMR spectroscopy and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group P21/c, having one symmetry-independent Hg2+ ion coordinated in a distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff ba se ligand (3,4-MeO-Bza)2En acts as a chelating ligand and coordinates via two N atoms to the mercury center.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP204%2F11%2F0809" target="_blank" >GAP204/11/0809: Absorption, beam homogeneity and varying irradiated volume corrections in multidomain bulk and thin film samples.</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Russian Journal of Coordination Chemistry
ISSN
1070-3284
e-ISSN
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Volume of the periodical
39
Issue of the periodical within the volume
1
Country of publishing house
RU - RUSSIAN FEDERATION
Number of pages
5
Pages from-to
104-108
UT code for WoS article
000312907700017
EID of the result in the Scopus database
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