Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00391677" target="_blank" >RIV/68378271:_____/13:00391677 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1134/S1070328412090047" target="_blank" >http://dx.doi.org/10.1134/S1070328412090047</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S1070328412090047" target="_blank" >10.1134/S1070328412090047</a>

Result language
angličtina
Original language name
Diiodo{N,N´-bis(2,3,4-trimethoxybenzaldehyde)-ethylenediimine}mercury(II): synthesis and crystal structure
Original language description
Mononuclear mercury(II) complex [Hg((2,3,4-MeO-Ba)2En)I2], where (2,3,4-MeO-Ba)2En =N,N'-bis(2,3,4-trimethoxybenzaldehyde)ethylenediimine, has been synthesized and characterized by elemental analysis (C, H, and N) and confirmed by single-crystal X-ray diffraction analysis. The complex crystallizes in the monoclinic system, with space group C2/c, having one symmetry-independent Hg2+ ion coordinated in distorted tetrahedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The Schiff base ligand (2,3,4-MeO-Ba)-22En acts as a chelating ligand and coordinates via two N atoms to the mercury center.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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