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The crystal chemistry of the uranyl carbonate mineral grimselite, (K,Na)3Na[(UO2)(CO3)3](H2O), from Jáchymov, Czech Republic

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00379239" target="_blank" >RIV/68378271:_____/12:00379239 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985831:_____/12:00379239 RIV/00023272:_____/12:#0001807 RIV/00216224:14310/12:00064320 RIV/00216208:11310/12:10130670

  • Result on the web

    <a href="http://dx.doi.org/10.1180/minmag.2012.076.3.01" target="_blank" >http://dx.doi.org/10.1180/minmag.2012.076.3.01</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1180/minmag.2012.076.3.01" target="_blank" >10.1180/minmag.2012.076.3.01</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    The crystal chemistry of the uranyl carbonate mineral grimselite, (K,Na)3Na[(UO2)(CO3)3](H2O), from Jáchymov, Czech Republic

  • Original language description

    Two crystals of the uranyl carbonate mineral grimselite, ideally K3Na[(UO2)(CO3)3](H2O), from Jáchymov in the Czech Republic were studied by single-crystal X-ray diffraction and electron-probe microanalysis. One crystal has considerably more Na than theideal chemical composition due to substitution of Na into KO8 polyhedra; the composition of the other crystal is nearer to ideal, and similar to synthetic grimselite. The presence of Na atoms in KO8 polyhedra, which are located in channels in the crystalstructure, reduces their volume, and as a result the unit-cell volume also decreases. Structure refinement shows that the formula for the sample with the anomalously high Na content is (K2.43Na0.57)<?3.00Na[(UO2)(CO3)3](H2O).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP204%2F11%2F0809" target="_blank" >GAP204/11/0809: Absorption, beam homogeneity and varying irradiated volume corrections in multidomain bulk and thin film samples.</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Mineralogical Magazine

  • ISSN

    0026-461X

  • e-ISSN

  • Volume of the periodical

    76

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    443-453

  • UT code for WoS article

    000306617900001

  • EID of the result in the Scopus database