A novel mononuclear square-planar copper(II) complex (Pip-H+)2[CuL4]2- with 2-cyano-3-(2,5-dimethoxyphenyl)acrylic acid as ligand: synthesis, crystal structures, spectral and thermal studies

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00380271" target="_blank" >RIV/68378271:_____/12:00380271 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s00706-011-0629-9" target="_blank" >http://dx.doi.org/10.1007/s00706-011-0629-9</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s00706-011-0629-9" target="_blank" >10.1007/s00706-011-0629-9</a>

Result language

angličtina

Original language name

A novel mononuclear square-planar copper(II) complex (Pip-H+)2[CuL4]2- with 2-cyano-3-(2,5-dimethoxyphenyl)acrylic acid as ligand: synthesis, crystal structures, spectral and thermal studies

Original language description

2-Cyano-3-(2,5-dimethoxyphenyl)acrylic acid and its novel mononuclear square-planar copper(II) complex dipiperidinium tetrakis[2-cyano-3-(2,5-dimethoxyphenyl)-acrylic acid]copper(II) (Pip-H+)2[CuL4]2- were synthesized and characterized by elemental analyses, FT?IR, UV?Vis spectroscopy, and thermogravimetric analysis. Moreover, the ligand was characterized by 1H and 13C NMR spectroscopy. The structures of the ligand and its copper(II)complex were confirmed by single-crystal X-ray crystallography. Whereasthe ligand crystallizes in the triclinic space group P-1 with unit cell parameters a = 4.6911(2) A, b = 9.0181(4) A, c = 13.7084(6) A, ? = 74.946(4)°, ? = 87.152(4)°, ? = 89.220(4) °, the complex crystallizes in the orthorhombic space group Pccn with unit cell parameters a = 27.5486(5) A , b = 12.9484(2) A, c = 15.8822(3) A.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Monatshefte fur Chemie

ISSN

0026-9247

e-ISSN

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Volume of the periodical

143

Issue of the periodical within the volume

5

Country of publishing house

AT - AUSTRIA

Number of pages

9

Pages from-to

753-761

UT code for WoS article

000302751300009

EID of the result in the Scopus database

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