New ?-OAC bridged dinuclear copper(II) complex with tridentate Schiff base ligand: synthesis, characterization, crystal structure, and CuO nano-particles formation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00451304" target="_blank" >RIV/68378271:_____/15:00451304 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1134/S1070328415070027" target="_blank" >http://dx.doi.org/10.1134/S1070328415070027</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S1070328415070027" target="_blank" >10.1134/S1070328415070027</a>
Alternative languages
Result language
angličtina
Original language name
New ?-OAC bridged dinuclear copper(II) complex with tridentate Schiff base ligand: synthesis, characterization, crystal structure, and CuO nano-particles formation
Original language description
A new (?acetato)bridged dinuclear copper(II) complex [Cu2(L)2(?-OAc)2] (I) has been synthe sized by the reaction of a tridentate N2O Schiff base ligand (HL) with Cu(OAC)2 in methanol at refluxed con ditions and characterized by elemental analysis (CHN) and FTIR spectroscopy. The crystal structure of I was investigated by single crystal Xray diffraction (CIF file CCDC no. 1013907). Xray results showed that two OAC groups bridge the copper(II) ions in a Cu2O2 core of a binuclear complex. Each copper(II) ion adopts a distorted square pyramidal geometry with one imine nitrogen, one amine nitrogen and one phenolato oxygen from the tridentate Schiff base ligand, completed by two acetate oxygen atoms. Finally, the complex was ther mally decomposed in order toobtain CuO nanoparticles.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Russian Journal of Coordination Chemistry
ISSN
1070-3284
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
7
Country of publishing house
RU - RUSSIAN FEDERATION
Number of pages
6
Pages from-to
456-461
UT code for WoS article
000356777200007
EID of the result in the Scopus database
2-s2.0-84935018396