Combination of pyridinium and isoquinolinium ylides with phenylisocyanate and isothiocyanates: Synthesis, characterisation, and X-ray crystal structures of mesoionic monosubstituted 3-oxo-propanamides or thioamides
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00455930" target="_blank" >RIV/68378271:_____/15:00455930 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1071/CH15113" target="_blank" >http://dx.doi.org/10.1071/CH15113</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1071/CH15113" target="_blank" >10.1071/CH15113</a>
Alternative languages
Result language
angličtina
Original language name
Combination of pyridinium and isoquinolinium ylides with phenylisocyanate and isothiocyanates: Synthesis, characterisation, and X-ray crystal structures of mesoionic monosubstituted 3-oxo-propanamides or thioamides
Original language description
Pyridinium ylides derived from 2-bromoacetophenone or methyl bromoacetate have been reacted with phenylisocyanate, phenyl- or methylisothiocyanate to afford mesoionic monosubstituted 3-oxo-propanamides or thioamides, via selfprotonation of the intermediate N-anion. A similar reaction under the same conditions of isoquinolinium ylides with phenylisocyanate or phenyisothiocyante also produced the corresponding mesoionic compounds. In order to establish the exact structure of the mesoionic compounds, single crystal X-ray structures were obtained for three of the pyridinium ylides. Crystal structure; ylides; selfprotonation; mesoionic componds
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GA15-12653S" target="_blank" >GA15-12653S: Validation and Interpretation of Modulated Structures</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Australian Journal of Chemistry
ISSN
0004-9425
e-ISSN
—
Volume of the periodical
68
Issue of the periodical within the volume
10
Country of publishing house
AU - AUSTRALIA
Number of pages
6
Pages from-to
1577-1582
UT code for WoS article
000362573700017
EID of the result in the Scopus database
2-s2.0-84943613374