Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00456263" target="_blank" >RIV/68378271:_____/15:00456263 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c5ra17249g" target="_blank" >http://dx.doi.org/10.1039/c5ra17249g</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5ra17249g" target="_blank" >10.1039/c5ra17249g</a>

Result language
angličtina
Original language name
Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts
Original language description
The reaction of 3-phenylpropylamine with Pd(OAc)2 by heating in toluene resulted in the nearly squareplanar complex trans-[Pd(C6H5(CH2)3NH2)2(OAc)2] (1). Complex 1 reacted with NaCl in methanol to obtain the corresponding product trans-[Pd(C6H5(CH2)3NH2)2Cl2] (2). Treatment of 2 with triphenylphosphine in dichloromethane afforded trans-[Pd(C6H5(CH2)3NH2)2(PPh3)2]2Cl (3). All the palladium(II) complexes (1?3) were fully characterized by IR and NMR spectroscopy. In addition, the crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
<a href="/en/project/GA15-12653S" target="_blank" >GA15-12653S: Validation and Interpretation of Modulated Structures</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)