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Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00456263" target="_blank" >RIV/68378271:_____/15:00456263 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c5ra17249g" target="_blank" >http://dx.doi.org/10.1039/c5ra17249g</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c5ra17249g" target="_blank" >10.1039/c5ra17249g</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Palladium complexes with 3-phenylpropylamine ligands: synthesis, structures, theoretical studies and application in the aerobic oxidation of alcohols as heterogeneous catalysts

  • Original language description

    The reaction of 3-phenylpropylamine with Pd(OAc)2 by heating in toluene resulted in the nearly squareplanar complex trans-[Pd(C6H5(CH2)3NH2)2(OAc)2] (1). Complex 1 reacted with NaCl in methanol to obtain the corresponding product trans-[Pd(C6H5(CH2)3NH2)2Cl2] (2). Treatment of 2 with triphenylphosphine in dichloromethane afforded trans-[Pd(C6H5(CH2)3NH2)2(PPh3)2]2Cl (3). All the palladium(II) complexes (1?3) were fully characterized by IR and NMR spectroscopy. In addition, the crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CC - Organic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA15-12653S" target="_blank" >GA15-12653S: Validation and Interpretation of Modulated Structures</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    RSC Advances

  • ISSN

    2046-2069

  • e-ISSN

  • Volume of the periodical

    5

  • Issue of the periodical within the volume

    124

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    12

  • Pages from-to

    102424-102435

  • UT code for WoS article

    000366162300037

  • EID of the result in the Scopus database

    2-s2.0-84948781567