Mo-II Cluster Complex-Based Coordination Polymer as an Efficient Heterogeneous Catalyst in the Suzuki–Miyaura Coupling Reaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00462104" target="_blank" >RIV/68378271:_____/16:00462104 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/16:00462104 RIV/44555601:13520/16:43887941
Result on the web
<a href="http://dx.doi.org/10.1002/ejic.201600704" target="_blank" >http://dx.doi.org/10.1002/ejic.201600704</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/ejic.201600704" target="_blank" >10.1002/ejic.201600704</a>
Alternative languages
Result language
angličtina
Original language name
Mo-II Cluster Complex-Based Coordination Polymer as an Efficient Heterogeneous Catalyst in the Suzuki–Miyaura Coupling Reaction
Original language description
The design and preparation of highly active heterogeneous palladium catalysts is attracting ever-increasing attention. In this paper, we report on the self-assembly of palladium centers and an octahedral molybdenum cluster complex bearing phosphine terminal ligands. This leads to a coordination polymer exhibiting high catalytic activity in the Suzuki–Miyaura cross-coupling reaction. The coordination polymer achieved a turnover number of 15800 in a reaction of deactivated aryl bromides with phenylboronic acid. Because metal clusters represent rare building blocks for the preparation of heterogeneous palladium catalysts, this work points to new structural motives that can be utilized to develop highly active heterogeneous catalysts.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
European Journal of Inorganic Chemistry
ISSN
1434-1948
e-ISSN
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Volume of the periodical
2016
Issue of the periodical within the volume
28
Country of publishing house
DE - GERMANY
Number of pages
6
Pages from-to
4668-4673
UT code for WoS article
000386169600019
EID of the result in the Scopus database
2-s2.0-84989888521