1D polymeric copper(I) and dinuclear silver(I) complexes of a bidentate Schiff base ligand: synthesis, spectroscopic characterization and thermal studies

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00465543" target="_blank" >RIV/68378271:_____/16:00465543 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2016.08.007" target="_blank" >http://dx.doi.org/10.1016/j.poly.2016.08.007</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2016.08.007" target="_blank" >10.1016/j.poly.2016.08.007</a>

Result language
angličtina
Original language name
1D polymeric copper(I) and dinuclear silver(I) complexes of a bidentate Schiff base ligand: synthesis, spectroscopic characterization and thermal studies
Original language description
One-dimensional polymeric copper(I) complex [Cu((NO2-ba)2en)(mi-I)]n ( 1) and dinuclear silver(I) complex [Ag((NO2-ba)2en)(mi-ONO2)]2 ( 2), where {(NO2-ba)2en = N,N’-bis(4-nitrobenzaldehyde)ethane-1,2-diamine}, were synthesized, characterized by elemental analysis (CHN), FT-IR and 1H NMR spectroscopy, thermal analysis and their structure were confirmed by single crystal X-ray diffraction analysis. The Schiff base acts as NN-bidentate chelating ligand coordinated to Cu(I) and Ag(I) ions. The complex 1 has a polymeric structure involving mi-I bridges while complex 2 has di-nuclear structure invol ving mi-O bridges with a molar proportion 1:1 of Cu(I) or Ag(I) to the Schiff base ligand.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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