Three variants of novel Co(II) complex with NSAID mefenamic acid and N,N'-donor ligand neocuproine
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00470088" target="_blank" >RIV/68378271:_____/16:00470088 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1515/zkri-2016-1991" target="_blank" >http://dx.doi.org/10.1515/zkri-2016-1991</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1515/zkri-2016-1991" target="_blank" >10.1515/zkri-2016-1991</a>
Alternative languages
Result language
angličtina
Original language name
Three variants of novel Co(II) complex with NSAID mefenamic acid and N,N'-donor ligand neocuproine
Original language description
Three variants of novel cobalt(II) complex with deprotonated mefenamic acid (mef) and N, N'- donor ligand neocuproine (neo) are described, namely; two differently colored and shaped crystal polymorphs of complex [Co(mef)(2) (neo)] (1a and 1b) and a pyridine solvate [Co(mef)(2) (neo)].py (2). The complexes have been characterized by infrared and UV- VIS spectroscopy, elemental analysis and single- crystal X- ray structure analysis. Although the complexes 1a, 1b and 2 crystallize in different crystal systems and space groups and differ in shapes of coordination polyhedra, the crystal structures of all three complexes contain analogous neutral units with Co(II) atom hexacoordinated by two chelate bonded mefenamato ligands and one chelate bonded neocuproine ligand, yielding CoN2O4 chromophore. The main structural difference between 1a, 1b and 2 is the conformation of the coordinated mef ligands, which affects the crystal packing of the complexes.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Zeitschrift fur Kristallographie-Crystalline Materials
ISSN
2194-4946
e-ISSN
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Volume of the periodical
231
Issue of the periodical within the volume
12
Country of publishing house
DE - GERMANY
Number of pages
10
Pages from-to
715-724
UT code for WoS article
000389672100003
EID of the result in the Scopus database
2-s2.0-84999231128