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Three variants of novel Co(II) complex with NSAID mefenamic acid and N,N'-donor ligand neocuproine

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00470088" target="_blank" >RIV/68378271:_____/16:00470088 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1515/zkri-2016-1991" target="_blank" >http://dx.doi.org/10.1515/zkri-2016-1991</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1515/zkri-2016-1991" target="_blank" >10.1515/zkri-2016-1991</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Three variants of novel Co(II) complex with NSAID mefenamic acid and N,N'-donor ligand neocuproine

  • Original language description

    Three variants of novel cobalt(II) complex with deprotonated mefenamic acid (mef) and N, N'- donor ligand neocuproine (neo) are described, namely; two differently colored and shaped crystal polymorphs of complex [Co(mef)(2) (neo)] (1a and 1b) and a pyridine solvate [Co(mef)(2) (neo)].py (2). The complexes have been characterized by infrared and UV- VIS spectroscopy, elemental analysis and single- crystal X- ray structure analysis. Although the complexes 1a, 1b and 2 crystallize in different crystal systems and space groups and differ in shapes of coordination polyhedra, the crystal structures of all three complexes contain analogous neutral units with Co(II) atom hexacoordinated by two chelate bonded mefenamato ligands and one chelate bonded neocuproine ligand, yielding CoN2O4 chromophore. The main structural difference between 1a, 1b and 2 is the conformation of the coordinated mef ligands, which affects the crystal packing of the complexes.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Zeitschrift fur Kristallographie-Crystalline Materials

  • ISSN

    2194-4946

  • e-ISSN

  • Volume of the periodical

    231

  • Issue of the periodical within the volume

    12

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    10

  • Pages from-to

    715-724

  • UT code for WoS article

    000389672100003

  • EID of the result in the Scopus database

    2-s2.0-84999231128