Pentacoordinate mixed-ligand Zn(II) complexes with flufenamato and niflumato ligands: crystal structure, spectral characterization and biological properties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F23%3A00577700" target="_blank" >RIV/68378271:_____/23:00577700 - isvavai.cz</a>
Result on the web
<a href="https://hdl.handle.net/11104/0346821" target="_blank" >https://hdl.handle.net/11104/0346821</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/cryst13101460" target="_blank" >10.3390/cryst13101460</a>
Alternative languages
Result language
angličtina
Original language name
Pentacoordinate mixed-ligand Zn(II) complexes with flufenamato and niflumato ligands: crystal structure, spectral characterization and biological properties
Original language description
Mixed-ligand complexes featuring a carboxylato ligand and bidentate chelate N,N'-donor ligands along with a single halogenido ligand are rarely subjected to studies despite their interesting physical, chemical and biological properties. A direct synthesis involving non-steroidal anti-inflammatory drugs flufenamic acid and niflumic acid and sterically hindering N,N'-donor ligands (neocuproine and 2,2'-biquinoline) has been used to prepare mononuclear mixed-ligand zinc complexes with a composition of [ZnCl(flu)(neo)] (1A and 1B) and [ZnCl(nif )(biq)] (2). Single-crystal X-ray diffraction data have shown that the carboxylate binding mode differs in the two polymorphs 1A and 1B, which form molecules of same composition, and the deviations in molecular geometry are further reflected in their supramolecular structures.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/LM2023065" target="_blank" >LM2023065: Material growth and measurement laboratory</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2023
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Crystals
ISSN
2073-4352
e-ISSN
2073-4352
Volume of the periodical
13
Issue of the periodical within the volume
10
Country of publishing house
CH - SWITZERLAND
Number of pages
18
Pages from-to
1460
UT code for WoS article
001092489900001
EID of the result in the Scopus database
2-s2.0-85175186514