mu(2)-Oxido bridged dinuclear vanadium(V) complex: synthesis and characterization

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473783" target="_blank" >RIV/68378271:_____/17:00473783 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2016.10.024" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2016.10.024</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2016.10.024" target="_blank" >10.1016/j.molstruc.2016.10.024</a>

Result language
angličtina
Original language name
mu(2)-Oxido bridged dinuclear vanadium(V) complex: synthesis and characterization
Original language description
mu(2)-Oxido bridged dinuclear vanadium(V) Schiff base complex with the general formula [VO2(L)](2)center dot 2-CH3OH was synthesized and characterized. The X-ray results show the complex is dinuclear with two mu-O bridging ions, and the vanadium centers have an octahedral N2O4 coordination sphere. The tridentate Schiff base ligand L coordinated to vanadium(V) center as a monoanion in the basal plane. The basal plane is completed by one of the mu-O bridges. The other mu-O bridge coordinated to vanadium(V) center as apical direction. The two oxido bridged connected the two V-v centers together with the V-v-O-V-v angle of 101.21(6), the V-O distances of 1.70(6) and 231(7) angstrom and the V...V separation of 3.113(5) angstrom. Finally, the complex was calcinated at 600 degrees C for 3 h. The FT-IR spectrum of the product shows the formation of the V2O5 particles.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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