Reactions of copper(II), nickel(II), and zinc(II) acetates with a new water-soluble 4-phenylthiosemicarbazone Schiff base ligand: synthesis, characterization, unexpected cyclization, antimicrobial, antioxidant, and anticancer activities

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473836" target="_blank" >RIV/68378271:_____/17:00473836 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2016.12.004" target="_blank" >http://dx.doi.org/10.1016/j.poly.2016.12.004</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2016.12.004" target="_blank" >10.1016/j.poly.2016.12.004</a>

Result language
angličtina
Original language name
Reactions of copper(II), nickel(II), and zinc(II) acetates with a new water-soluble 4-phenylthiosemicarbazone Schiff base ligand: synthesis, characterization, unexpected cyclization, antimicrobial, antioxidant, and anticancer activities
Original language description
A new Schiff base thiosemicarbazone ligand with aqueous solubility, namely, sodium 3-{[(anilinocarbonothioyl)hydrazono]methyl}-4-hydroxy benzene sulfonate (NaH2L) was synthesized by condensation of 4-phenylthiosemicarbazide and sodium salicylaldehyde-5-sulfonate (NaSalSO3) and characterized by elemental analysis, spectroscopic methods (UV–Vis, 1H NMR, FTIR) and electrospray ionization mass spectrometry. A co-crystal (Na(H2L)·Na(SalSO3)) of NaH2L and NaSalSO3 was prepared which confirmed the expected structure of the ligand. Reactions of NaH2L·0.5H2O with copper(II), nickel(II), and zinc(II) acetates were investigated under reflux conditions in methanol to produce following complexes [Cu2(Lcycl)2(H2O)2]·2H2O (CuLcycl), Ni(HL)(H2O)3 (NiL), and Zn(HL)(H2O)3 (ZnL).
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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