Synthesis, characterization and in vitro biological activities of new water-soluble copper(II), zinc(II), and nickel(II) complexes with sulfonato-substituted Schiff base ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473837" target="_blank" >RIV/68378271:_____/17:00473837 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2017.01.005" target="_blank" >http://dx.doi.org/10.1016/j.ica.2017.01.005</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2017.01.005" target="_blank" >10.1016/j.ica.2017.01.005</a>

Result language
angličtina
Original language name
Synthesis, characterization and in vitro biological activities of new water-soluble copper(II), zinc(II), and nickel(II) complexes with sulfonato-substituted Schiff base ligand
Original language description
A water-soluble thiosemicarbazone Schiff base ligand, namely sodium 3-{[(aminocarbonothioyl)hydrazono]methyl}-4-hydroxybenzenesulfonate (NaH2L) was prepared by 1:1 condensation of sodium salicylaldehyde-5-sulfonate and thiosemicarbazide. The X-ray structure analysis of NaH2L shows that the organic fragments of the ligand are bridged by two different types of seven-coordinated sodium cations. The ligand was used in the synthesis of the following CuII, NiII, and ZnII complexes: [Cu2(HL)2(H2O)3] (1), Ni(HL)(H2O)1.5 (2), and Zn(HL)(H2O)2 (3). The metal complexes were characterized by physico-chemical and spectroscopic methods. The X-ray structure analysis of the dinuclear copper complex (1) shows that two metal centers are five coordinated having distorted square pyramidal geometries.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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