The non-coordinating anion 1,1,3,3-tetracyano-2-propoxy-propenide as an anion-pi donor in cis-diaquabis(2,2 '-dipyridylamine)zinc and its cadmium analog: luminescence properties, Hirshfeld analysis and central-atom induced polymorphism
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00479397" target="_blank" >RIV/68378271:_____/17:00479397 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2017.04.020" target="_blank" >http://dx.doi.org/10.1016/j.poly.2017.04.020</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2017.04.020" target="_blank" >10.1016/j.poly.2017.04.020</a>
Alternative languages
Result language
angličtina
Original language name
The non-coordinating anion 1,1,3,3-tetracyano-2-propoxy-propenide as an anion-pi donor in cis-diaquabis(2,2 '-dipyridylamine)zinc and its cadmium analog: luminescence properties, Hirshfeld analysis and central-atom induced polymorphism
Original language description
The synthesis, structure and properties of cis-diaquabis(2,2'-dipyridylamine)zinc bis(1,1,3,3-tetracyano-2-propoxy-propenide),[Zn(H2O)(2)(2,2'-dpa)(2)][tcnopr](2), I, and its isomorphous Cd analog, are reported. These two coordination compounds were prepared through hydrothermal reactions of Zn(II)/Cd(II) acetate with potassium 1,1,3,3-tetracyano-2-propoxy-propenide (tcnopr = [(NC)(2)CC(OPr)C(CN)(2)](-)) in the presence of 2,2'-dipyridylamine (dpa = C10H9N3) as a co-ligand. Both new compounds were fully characterized by elemental analysis, FT-IR spectroscopy, powder XRD and X-ray single-crystal diffraction.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
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Volume of the periodical
131
Issue of the periodical within the volume
Jul
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
27-33
UT code for WoS article
000403519300005
EID of the result in the Scopus database
2-s2.0-85019052425