Phase transitions of Cu3+xSi observed by temperature-dependent x-ray powder diffraction
Result description
Phases in the system Cu3+xSi were analyzed by temperature-dependent x-ray powder diffraction and differential scanning calorimetry on samples with nominal composition Cu74Si26 and Cu78Si22 in the temperature range between 30 °C and 700 °C. Contrary to previous works, which report three phases in the system, we identified six distinct phases, labeled, in order of increasing temperature, η‴, η″, η′, η3, η2, η1. All these phases can be indexed with a similar basic unit cell. However, each phase has a different superstructure or modulation vectors.
Keywords
X-ray powder diffractiondifferential scanning calorimetryphase transitionsCu3+xSi
The result's identifiers
Result code in IS VaVaI
Alternative codes found
RIV/00216208:11320/17:10371415
Result on the web
DOI - Digital Object Identifier
Alternative languages
Result language
angličtina
Original language name
Phase transitions of Cu3+xSi observed by temperature-dependent x-ray powder diffraction
Original language description
Phases in the system Cu3+xSi were analyzed by temperature-dependent x-ray powder diffraction and differential scanning calorimetry on samples with nominal composition Cu74Si26 and Cu78Si22 in the temperature range between 30 °C and 700 °C. Contrary to previous works, which report three phases in the system, we identified six distinct phases, labeled, in order of increasing temperature, η‴, η″, η′, η3, η2, η1. All these phases can be indexed with a similar basic unit cell. However, each phase has a different superstructure or modulation vectors.
Czech name
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Czech description
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Classification
Type
Jimp - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Intermetallics
ISSN
0966-9795
e-ISSN
—
Volume of the periodical
91
Issue of the periodical within the volume
Dec
Country of publishing house
GB - UNITED KINGDOM
Number of pages
11
Pages from-to
129-139
UT code for WoS article
000413386700019
EID of the result in the Scopus database
2-s2.0-85029093675
Basic information
Result type
Jimp - Article in a specialist periodical, which is included in the Web of Science database
OECD FORD
Condensed matter physics (including formerly solid state physics, supercond.)
Year of implementation
2017