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Phase transitions of Cu3+xSi observed by temperature-dependent x-ray powder diffraction

Result description

Phases in the system Cu3+xSi were analyzed by temperature-dependent x-ray powder diffraction and differential scanning calorimetry on samples with nominal composition Cu74Si26 and Cu78Si22 in the temperature range between 30 °C and 700 °C. Contrary to previous works, which report three phases in the system, we identified six distinct phases, labeled, in order of increasing temperature, η‴, η″, η′, η3, η2, η1. All these phases can be indexed with a similar basic unit cell. However, each phase has a different superstructure or modulation vectors.

Keywords

X-ray powder diffractiondifferential scanning calorimetryphase transitionsCu3+xSi

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    Phase transitions of Cu3+xSi observed by temperature-dependent x-ray powder diffraction

  • Original language description

    Phases in the system Cu3+xSi were analyzed by temperature-dependent x-ray powder diffraction and differential scanning calorimetry on samples with nominal composition Cu74Si26 and Cu78Si22 in the temperature range between 30 °C and 700 °C. Contrary to previous works, which report three phases in the system, we identified six distinct phases, labeled, in order of increasing temperature, η‴, η″, η′, η3, η2, η1. All these phases can be indexed with a similar basic unit cell. However, each phase has a different superstructure or modulation vectors.

  • Czech name

  • Czech description

Classification

  • Type

    Jimp - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

Others

  • Publication year

    2017

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Intermetallics

  • ISSN

    0966-9795

  • e-ISSN

  • Volume of the periodical

    91

  • Issue of the periodical within the volume

    Dec

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    11

  • Pages from-to

    129-139

  • UT code for WoS article

    000413386700019

  • EID of the result in the Scopus database

    2-s2.0-85029093675

Basic information

Result type

Jimp - Article in a specialist periodical, which is included in the Web of Science database

Jimp

OECD FORD

Condensed matter physics (including formerly solid state physics, supercond.)

Year of implementation

2017