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Electric-field-induced phase transition and pinched P-E hysteresis loops in Pb-free ferroelectrics with a tungsten bronze structure

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F18%3A00492452" target="_blank" >RIV/68378271:_____/18:00492452 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1038/s41427-018-0013-x" target="_blank" >http://dx.doi.org/10.1038/s41427-018-0013-x</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1038/s41427-018-0013-x" target="_blank" >10.1038/s41427-018-0013-x</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electric-field-induced phase transition and pinched P-E hysteresis loops in Pb-free ferroelectrics with a tungsten bronze structure

  • Original language description

    We report the discovery of pinched, polarization-vs.-electric field (P-E) hysteresis loops in the lead-free tungsten bronze ferroelectrics Ba4Sm2Ti4Nb6O30 and Ba4Eu2Ti4Nb6O30, while a broad, single P-E hysteresis loop was observed in the analogue compound Ba4Nd2Ti4Nb6O30. Pinched P-E loops are similar to antiferroelectric hysteresis loops, but in perovskites, they are mostly caused by an extrinsic, internal bias field due to defects, which block domain wall motion. We show that the pinched P-E loops are caused by an intrinsic effect, i.e., by the electric-field-induced phase transition from a non-polar incommensurate to a polar commensurately modulated crystal structure.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    NPG Asia Materials

  • ISSN

    1884-4049

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    Apr

  • Country of publishing house

    JP - JAPAN

  • Number of pages

    11

  • Pages from-to

  • UT code for WoS article

    000438870700001

  • EID of the result in the Scopus database

    2-s2.0-85045112215