Aromatic azide transformation on the Ag(111) surface studied by scanning probe microscopy

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00509519" target="_blank" >RIV/68378271:_____/19:00509519 - isvavai.cz</a>
Alternative codes found
RIV/61388963:_____/19:00509519 RIV/61989592:15310/19:73597606
Result on the web
<a href="https://doi.org/10.1002/anie.201812334" target="_blank" >https://doi.org/10.1002/anie.201812334</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.201812334" target="_blank" >10.1002/anie.201812334</a>

Result language
angličtina
Original language name
Aromatic azide transformation on the Ag(111) surface studied by scanning probe microscopy
Original language description
Chemical transformation of 9‐azidophenanthrene on the Ag(111) surface was studied by nc‐AFM in UHV. High‐resolution imaging supported by first‐principle calculations revealed the structure of the final products that originated from a common and elusive 9‐phenanthryl nitrenoid intermediate chemisorbed on the Ag(111) surface. A formal nitrene insertion into the C−H bond along with its dimerisation and hydrogenation were identified as main reaction channels. Thus, the ability of aryl azides to form covalent σ‐ and π‐bonds between their transformation products on a solid surface was demonstrated at a single‐molecule level.n
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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