Unusual scaffold rearrangement in polyaromatic hydrocarbons driven by concerted action of single gold atoms on a gold surface

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00565238" target="_blank" >RIV/68378271:_____/22:00565238 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/22:10457606 RIV/61989592:15310/22:73617327 RIV/61989592:15640/22:73617327
Result on the web
<a href="https://doi.org/10.1002/anie.202208010" target="_blank" >https://doi.org/10.1002/anie.202208010</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202208010" target="_blank" >10.1002/anie.202208010</a>

Result language
angličtina
Original language name
Unusual scaffold rearrangement in polyaromatic hydrocarbons driven by concerted action of single gold atoms on a gold surface
Original language description
In this work, we report the synthesis of a PAH molecule, formation of which consists of an unusual C-C bond cleavage accompanied by a complex π-conjugated molecular scaffold rearrangement. We demonstrate that the complex chemical transformation is steered by concerted motion of individual Au0 gold atoms on a supporting Au(111) surface. This observation underpins the importance of single-atom catalysis mediated by adatoms in on-surface synthesis as well as catalytic activity of single Au0 atoms facilitating cleavage of covalent carbon bonds.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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