Selective activation of aromatic C−H bonds catalyzed by single gold atoms at room temperature

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00564414" target="_blank" >RIV/68378271:_____/22:00564414 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/22:73616235 RIV/61989592:15640/22:73616235
Result on the web
<a href="https://doi.org/10.1021/jacs.2c10154" target="_blank" >https://doi.org/10.1021/jacs.2c10154</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jacs.2c10154" target="_blank" >10.1021/jacs.2c10154</a>

Result language
angličtina
Original language name
Selective activation of aromatic C−H bonds catalyzed by single gold atoms at room temperature
Original language description
Here, we examine the interaction between 9,10-dicyanoanthracene (DCA) molecules and Au adatoms on an Ag(111) surface at room temperature (RT). Characterization via low-temperature scanning tunneling microscopy, spectroscopy, and non-contact atomic force microscopy, supported by theoretical calculations, revealed the formation of organometallic DCA-Au-DCA units, where C atoms at the ends of the anthracene moieties are bonded covalently to single Au atoms. The formation of this organometallic compound is initiated by a regioselective cleaving of C-H bonds at RT.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10403 - Physical chemistry

Project
<a href="/en/project/GX20-13692X" target="_blank" >GX20-13692X: 1D molecular chains on surfaces</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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