Interaction of chiral and achiral dimethylsuccinic acid diastereomers with a Cu(110) surface
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00521233" target="_blank" >RIV/68378271:_____/19:00521233 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.jpcc.8b11320" target="_blank" >https://doi.org/10.1021/acs.jpcc.8b11320</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpcc.8b11320" target="_blank" >10.1021/acs.jpcc.8b11320</a>
Alternative languages
Result language
angličtina
Original language name
Interaction of chiral and achiral dimethylsuccinic acid diastereomers with a Cu(110) surface
Original language description
The transmission of chirality to an achiral metal surface after adsorption of chiral or achiral molecules is an exciting approach toward new materials systems. The interaction of racemic 2,3-dimethylsuccinic acid and its achiral meso form with a Cu(110) surface has been investigated in ultrahigh vacuum by means of X-ray photoelectron spectroscopy, low-energy electron diffraction, reflection absorption infrared spectroscopy, scanning tunneling microscopy, temperature-programmed desorption, and density functional theory. Racemic as well as meso-2,3-dimethylsuccinic acid form extended enantiomorphous structures, coexisting with extended two- dimensional structures that do not break the mirror symmetry of the substrate surface. Copper adatoms decorating the molecules suggest a chiral reconstruction of the surface. The thermally induced decomposition proceeds autocatalytically in a so-called surface explosion and shows a profound difference for the diastereomers.n
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/EF16_027%2F0008215" target="_blank" >EF16_027/0008215: IOP researches mobility</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry C
ISSN
1932-7447
e-ISSN
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Volume of the periodical
123
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
2329-2335
UT code for WoS article
000457816600033
EID of the result in the Scopus database
2-s2.0-85060307823