Chiral Surface from achiral ingredients: modification of Cu(110) with phthalic acid
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00521271" target="_blank" >RIV/68378271:_____/19:00521271 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.jpcc.9b00637" target="_blank" >https://doi.org/10.1021/acs.jpcc.9b00637</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpcc.9b00637" target="_blank" >10.1021/acs.jpcc.9b00637</a>
Alternative languages
Result language
angličtina
Original language name
Chiral Surface from achiral ingredients: modification of Cu(110) with phthalic acid
Original language description
The adsorption of dicarboxylic acids is a classical model approach for understanding molecular recognition at surfaces. The interaction of achiral phthalic acid with an achiral Cu(110) surface has been investigated in ultrahigh vacuum by means of scanning tunneling microscopy, low-energy electron diffraction, X-ray photoelectron spectroscopy, reflection absorption infrared spectroscopy, temperature-programmed desorption, and density functional theory. Different ordered domains at a length scale of several tens of nanometers are observed, of which three are enantiomorphous and therefore appear in two mirror-symmetric forms. Theoretical considerations suggest that spontaneous mirror-symmetry breaking occurs at the single-molecular level, in which the surface becomes also chirally distorted.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry C
ISSN
1932-7447
e-ISSN
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Volume of the periodical
123
Issue of the periodical within the volume
14
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
9121-9127
UT code for WoS article
000464768600071
EID of the result in the Scopus database
2-s2.0-85063439472