Crystal structure of a supramolecular dimer of Co(III) complex and evaluation of the DNA /BSA interaction
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00533048" target="_blank" >RIV/68378271:_____/20:00533048 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.molstruc.2019.127100" target="_blank" >https://doi.org/10.1016/j.molstruc.2019.127100</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2019.127100" target="_blank" >10.1016/j.molstruc.2019.127100</a>
Alternative languages
Result language
angličtina
Original language name
Crystal structure of a supramolecular dimer of Co(III) complex and evaluation of the DNA /BSA interaction
Original language description
The [Co(L)(H2O)2]ClO4 (where L denotes N,N0-Bis(3-methoxysalicylidene)-1,2-diaminopropane) was prepared, and its characterization was reported by single crystal X-ray crystallography, elemental analysis, mass spectrometry and spectroscopic methods (1H NMR, IR, and UVeVis). The crystal structure showed that the arrangement around cobalt atom is octahedral with two imine nitrogen atoms (N1, N2) and two oxygen atoms of a hydroxyl group (O2, O3) in equatorial positions and two water molecules at the axial positions. The hydrogen bonding interactions between a coordinated water molecule and phenoxo/methox y oxygens result in supermolecular dimers. Interaction of the complex with FS-DNA and protein (BSA) was explored by absorption and fluorescence spectroscopy.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Structure
ISSN
0022-2860
e-ISSN
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Volume of the periodical
1200
Issue of the periodical within the volume
Jan
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
15
Pages from-to
1-15
UT code for WoS article
000496810900068
EID of the result in the Scopus database
2-s2.0-85072851274