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Synthesis, solution stability, and structural characterization of quinolinol-based silver(I) complexes

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537741" target="_blank" >RIV/68378271:_____/20:00537741 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/20:10412428

  • Result on the web

    <a href="https://doi.org/10.1080/00958972.2020.1758681" target="_blank" >https://doi.org/10.1080/00958972.2020.1758681</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1080/00958972.2020.1758681" target="_blank" >10.1080/00958972.2020.1758681</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis, solution stability, and structural characterization of quinolinol-based silver(I) complexes

  • Original language description

    Three silver(I) complex compounds of halogen derivatives of 8-quinolinol (XQ), [Ag(HdClQ)2](NO3).CH3OH (1), [Ag(HdBrQ)2](NO3)(2), and [Ag(BrQ)]n(3), have been prepared with the aim to study their anticancer properties. All compounds were characterized by IR and NMR spectroscopy andelemental analysis. Single-crystal X-ray diffraction analysis revealed that crystal structure of1is ionic,2is molecular while 3 is polymeric. All three XQ ligands in 1–3 are N,O-chelate coordinated to the Ag(I) central atoms which are in a deformed square planar (1), distorted tetragonal pyramidal (2), or distorted triangular arrangement (3). Stability of all compounds in DMSO was proved by 1HNMR and UV-vis spectroscopy. Biological activity has not been studied because of limited solubility of prepared compounds in DMSO/water mixture.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    <a href="/en/project/LO1603" target="_blank" >LO1603: Centre of Technology and Advanced Structure Analysis of Materials with Application Impact</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Coordination Chemistry

  • ISSN

    0095-8972

  • e-ISSN

  • Volume of the periodical

    73

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    15

  • Pages from-to

    784-798

  • UT code for WoS article

    000534122400001

  • EID of the result in the Scopus database

    2-s2.0-85084845713