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How humidity and light exposure change the photophysics of metal halide perovskite solar cells

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537871" target="_blank" >RIV/68378271:_____/20:00537871 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21340/20:00345157

  • Result on the web

    <a href="https://doi.org/10.1002/solr.202000382" target="_blank" >https://doi.org/10.1002/solr.202000382</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/solr.202000382" target="_blank" >10.1002/solr.202000382</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    How humidity and light exposure change the photophysics of metal halide perovskite solar cells

  • Original language description

    Metal halide perovskites exhibit outstanding optical and electronic properties but are very sensitive to humidity and light-soaking. In this work, the photophysics of perovskites that have been exposed to such conditions are studied and the impact of excess lead iodide is revealed. For exposed samples, the formation of sub-bandgap states and increased trap assisted recombination is observed, using highly sensitive absorption and time-resolved photoluminescence measurements, respectively. It appears that such exposure primarily affects the perovskite surface. Consequently, on n–i–p device level, the spiro-OMeTAD/perovskite interface is more rapidly affected than its buried electron-collecting interface. Moreover, both stoichiometric and nonstoichiometric MAPbI3-based solar cells show reduced device performance mainly due to voltage losses. Overall, this study brings forward key points to consider in engineering perovskite solar cells with improved performance and material stability.n

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    SOL RRL

  • ISSN

    2367-198X

  • e-ISSN

  • Volume of the periodical

    4

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    10

  • Pages from-to

    1-10

  • UT code for WoS article

    000572068000001

  • EID of the result in the Scopus database

    2-s2.0-85091381917