A mixed-valent iron (II/III) diamond chain with single-ion anisotropy
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00539490" target="_blank" >RIV/68378271:_____/20:00539490 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.inorgchem.9b02616" target="_blank" >https://doi.org/10.1021/acs.inorgchem.9b02616</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.inorgchem.9b02616" target="_blank" >10.1021/acs.inorgchem.9b02616</a>
Alternative languages
Result language
angličtina
Original language name
A mixed-valent iron (II/III) diamond chain with single-ion anisotropy
Original language description
The geometrically frustrated diamond spin chain system has yielded materials with a diversity of interesting magnetic properties but is predominantly limited to compounds with single-spin components. Here, we report the compound [(CH3)2NH2]6[FeIII4FeII2(μ3-O)2(μ3-OH)2(μ3-SO4)8] (1), which features the mixed-valent iron(II/III) diamond chain: ∞[FeIII–(FeIII)2–FeIII–(FeII)2]. 57Fe Mössbauer spectroscopy shows that two-thirds of the total spins in the ∞[FeIII4FeII2] diamond chain are spin-5/2 (high-spin FeIII), while the remaining one-third are spin-2 (high-spin FeII). To date, 1 is the only diamond-chain compound composed of more than one type of dimer, namely, (FeIII)2 and (FeII)2.n
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry
ISSN
0020-1669
e-ISSN
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Volume of the periodical
59
Issue of the periodical within the volume
2
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
1068-1074
UT code for WoS article
000509420100016
EID of the result in the Scopus database
2-s2.0-85078387654