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A mixed-valent iron (II/III) diamond chain with single-ion anisotropy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00539490" target="_blank" >RIV/68378271:_____/20:00539490 - isvavai.cz</a>

  • Result on the web

    <a href="https://doi.org/10.1021/acs.inorgchem.9b02616" target="_blank" >https://doi.org/10.1021/acs.inorgchem.9b02616</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acs.inorgchem.9b02616" target="_blank" >10.1021/acs.inorgchem.9b02616</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    A mixed-valent iron (II/III) diamond chain with single-ion anisotropy

  • Original language description

    The geometrically frustrated diamond spin chain system has yielded materials with a diversity of interesting magnetic properties but is predominantly limited to compounds with single-spin components. Here, we report the compound [(CH3)2NH2]6[FeIII4FeII2(μ3-O)2(μ3-OH)2(μ3-SO4)8] (1), which features the mixed-valent iron(II/III) diamond chain: ∞[FeIII–(FeIII)2–FeIII–(FeII)2]. 57Fe Mössbauer spectroscopy shows that two-thirds of the total spins in the ∞[FeIII4FeII2] diamond chain are spin-5/2 (high-spin FeIII), while the remaining one-third are spin-2 (high-spin FeII). To date, 1 is the only diamond-chain compound composed of more than one type of dimer, namely, (FeIII)2 and (FeII)2.n

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10402 - Inorganic and nuclear chemistry

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganic Chemistry

  • ISSN

    0020-1669

  • e-ISSN

  • Volume of the periodical

    59

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    1068-1074

  • UT code for WoS article

    000509420100016

  • EID of the result in the Scopus database

    2-s2.0-85078387654