1D Coordination π–d conjugated polymers with distinct structures defined by the choice of the transition metal: towards a new class of antiaromatic macrocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00541649" target="_blank" >RIV/68378271:_____/21:00541649 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15640/21:73612430
Result on the web
<a href="https://doi.org/10.1002/anie.202011462" target="_blank" >https://doi.org/10.1002/anie.202011462</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202011462" target="_blank" >10.1002/anie.202011462</a>
Alternative languages
Result language
angličtina
Original language name
1D Coordination π–d conjugated polymers with distinct structures defined by the choice of the transition metal: towards a new class of antiaromatic macrocycles
Original language description
Recently π–d conjugated coordination polymers have received a lot of attention owing to their unique material properties, although synthesis of long and defect‐free polymers remains challenging. Herein we introduce a novel on‐surface synthesis of coordination polymers with quinoidal ligands under ultra‐high vacuum conditions, which enables formation of flexible coordination polymers with lengths up to hundreds of nanometers. Moreover, this procedure allows the incorporation of different transition‐metal atoms with four‐ or two‐fold coordination. Remarkably, the two‐fold coordination mode revealed the formation of wires constituted by (electronically) independent 12‐membered antiaromatic macrocycles linked together through two C−C single bonds.n
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
60
Issue of the periodical within the volume
1
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
439-445
UT code for WoS article
000584114800001
EID of the result in the Scopus database
2-s2.0-85096679868