1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F21%3A00349574" target="_blank" >RIV/68407700:21340/21:00349574 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/20:73604263
Result on the web
<a href="https://doi.org/10.1002/anie.202011462" target="_blank" >https://doi.org/10.1002/anie.202011462</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202011462" target="_blank" >10.1002/anie.202011462</a>
Alternative languages
Result language
angličtina
Original language name
1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles
Original language description
Recently pi-d conjugated coordination polymers have received a lot of attention owing to their unique material properties, although synthesis of long and defect-free polymers remains challenging. Herein we introduce a novel on-surface synthesis of coordination polymers with quinoidal ligands under ultra-high vacuum conditions, which enables formation of flexible coordination polymers with lengths up to hundreds of nanometers. Moreover, this procedure allows the incorporation of different transition-metal atoms with four- or two-fold coordination. Remarkably, the two-fold coordination mode revealed the formation of wires constituted by (electronically) independent 12-membered antiaromatic macrocycles linked together through two C-C single bonds.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie International Edition
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
60
Issue of the periodical within the volume
1
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
439-445
UT code for WoS article
000584114800001
EID of the result in the Scopus database
2-s2.0-85096679868