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1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68407700%3A21340%2F21%3A00349574" target="_blank" >RIV/68407700:21340/21:00349574 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/20:73604263

  • Result on the web

    <a href="https://doi.org/10.1002/anie.202011462" target="_blank" >https://doi.org/10.1002/anie.202011462</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/anie.202011462" target="_blank" >10.1002/anie.202011462</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    1D Coordination pi-d Conjugated Polymers with Distinct Structures Defined by the Choice of the Transition Metal: Towards a New Class of Antiaromatic Macrocycles

  • Original language description

    Recently pi-d conjugated coordination polymers have received a lot of attention owing to their unique material properties, although synthesis of long and defect-free polymers remains challenging. Herein we introduce a novel on-surface synthesis of coordination polymers with quinoidal ligands under ultra-high vacuum conditions, which enables formation of flexible coordination polymers with lengths up to hundreds of nanometers. Moreover, this procedure allows the incorporation of different transition-metal atoms with four- or two-fold coordination. Remarkably, the two-fold coordination mode revealed the formation of wires constituted by (electronically) independent 12-membered antiaromatic macrocycles linked together through two C-C single bonds.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Angewandte Chemie International Edition

  • ISSN

    1433-7851

  • e-ISSN

    1521-3773

  • Volume of the periodical

    60

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    439-445

  • UT code for WoS article

    000584114800001

  • EID of the result in the Scopus database

    2-s2.0-85096679868