Catalytic oxidation of organic sulfides by new iron-chloro Schiff base complexes: The effect of methoxy substitution and ligand isomerism on the electronic, electrochemical and catalytic performance of the complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00541705" target="_blank" >RIV/68378271:_____/21:00541705 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.poly.2021.115135" target="_blank" >https://doi.org/10.1016/j.poly.2021.115135</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2021.115135" target="_blank" >10.1016/j.poly.2021.115135</a>
Alternative languages
Result language
angličtina
Original language name
Catalytic oxidation of organic sulfides by new iron-chloro Schiff base complexes: The effect of methoxy substitution and ligand isomerism on the electronic, electrochemical and catalytic performance of the complexes
Original language description
Four new Fe(III)-Chloro Schiff base complexes were synthesized and characterized. The N2O2 type tetradentate Schiff base ligands were synthesized from the condensation of meso-1,2-diphenyl-1,2-ethylenediamine with salicylaldehyde (H2L1), 3-methoxysalicylaldehyde (H2L2), 4-methoxysalicylaldehyde (H2L3) and 5-methoxysalicylaldehyde (H2L4). The corresponding iron-chloro complexes with the general formula [Fe(Ln)Cl] (n = 1–4 for complexes (1–4)) were characterized by FTIR and UV–Vis spectroscopy and elemental analysis. Crystal structure of (1) was obtained by single-crystal X-ray crystallograph y. Cyclic voltammetry was used to study the electrochemistry of the complexes.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Polyhedron
ISSN
0277-5387
e-ISSN
1873-3719
Volume of the periodical
200
Issue of the periodical within the volume
May
Country of publishing house
GB - UNITED KINGDOM
Number of pages
8
Pages from-to
115135
UT code for WoS article
000640386000008
EID of the result in the Scopus database
2-s2.0-85102319386