Mn(III) complexes with nitro-substituted ligands—Spin states with a twist

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00543235" target="_blank" >RIV/68378271:_____/21:00543235 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0320491" target="_blank" >http://hdl.handle.net/11104/0320491</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1063/5.0050276" target="_blank" >10.1063/5.0050276</a>

Result language
angličtina
Original language name
Mn(III) complexes with nitro-substituted ligands—Spin states with a twist
Original language description
Structural, magnetic, and computational data on two new Mn(III) complex cations in lattices with five different counterions and varying levels of solvation are compared to investigate the influence of the position of the electron-withdrawing ligand nitro-substituent on the thermal spin crossover profile. The [MnL1]+ (a) and [MnL2]+ (b) complex cations were prepared by complexation of Mn(III) to the Schiff base chelates formed from condensation of 3-nitrosalicylaldehyde or 5-nitrosalicylaldehyde, respectively, with 1,2-bis(3-aminopropylamino)ethane and were crystallized with NO−3, (1a/b), ClO−4, (2a/b), PF−6, (3a/b), CF3SO−3 (4a/b), and BPh−4 (5a/b) counterions. Magnetostructural analysis reveals a minor trend in the spin state preference depending on the position of the nitro substituent where the orientation is dependent on crystal packing.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)