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Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F15%3A00439785" target="_blank" >RIV/61388980:_____/15:00439785 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216275:25310/15:39900118

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.ica.2014.10.006" target="_blank" >http://dx.doi.org/10.1016/j.ica.2014.10.006</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ica.2014.10.006" target="_blank" >10.1016/j.ica.2014.10.006</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands

  • Original language description

    New ionic manganese(II/III), manganese(III) and iron(II/III) complexes of the formula [Mn-II(H2O)(2)(phen)(2)]{[Mn-III(dipic)(2)]}(2)center dot 7H(2)O, (dmphenH)[Mn-III(dipic)(2)]center dot 2H(2)O, (2,2'-bipyH)[Mn-III(dipic)(2)]center dot 3H(2)O, (4,4'-bipyH)[Mn-III(dipic)(2)]center dot 4H(2)O, [Fe-II(phen)(3)]{[Fe-III(dipic)(2)]}(2)center dot 4.83H(2)O and [Fe-II(2,2'-bipy)(3)]{[Fe-III(dipic)(2)]}(2)center dot 6.11H(2)O where dipic(2-) = pyridine-2,6-dicarboxylate anion, phen = 1,10-phenanthroline, dmphenH = 2,9-dimethyl-1,10-phenanthrolinium cation, 2,2'-bipyH = 2-(2-pyridyl)pyridinium cation, 4,4'-bipyH = 4-(4-pyridyl)pyridinium cation, have been prepared and characterized by the single-crystal X-ray structure analysis, infrared spectroscopy, and bymagnetic susceptibility and magnetization measurements. A zero field splitting was found in the Mn(III) dipicolinates while an antiferromagnetic exchange interaction was present in the Fe(III) dipicolinates.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Inorganica chimica acta

  • ISSN

    0020-1693

  • e-ISSN

  • Volume of the periodical

    425

  • Issue of the periodical within the volume

    JAN

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    11

  • Pages from-to

    134-144

  • UT code for WoS article

    000345755700019

  • EID of the result in the Scopus database