Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F15%3A00439785" target="_blank" >RIV/61388980:_____/15:00439785 - isvavai.cz</a>
Alternative codes found
RIV/00216275:25310/15:39900118
Result on the web
<a href="http://dx.doi.org/10.1016/j.ica.2014.10.006" target="_blank" >http://dx.doi.org/10.1016/j.ica.2014.10.006</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.ica.2014.10.006" target="_blank" >10.1016/j.ica.2014.10.006</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis, structure and magnetism of manganese and iron dipicolinates with N,N '-donor ligands
Original language description
New ionic manganese(II/III), manganese(III) and iron(II/III) complexes of the formula [Mn-II(H2O)(2)(phen)(2)]{[Mn-III(dipic)(2)]}(2)center dot 7H(2)O, (dmphenH)[Mn-III(dipic)(2)]center dot 2H(2)O, (2,2'-bipyH)[Mn-III(dipic)(2)]center dot 3H(2)O, (4,4'-bipyH)[Mn-III(dipic)(2)]center dot 4H(2)O, [Fe-II(phen)(3)]{[Fe-III(dipic)(2)]}(2)center dot 4.83H(2)O and [Fe-II(2,2'-bipy)(3)]{[Fe-III(dipic)(2)]}(2)center dot 6.11H(2)O where dipic(2-) = pyridine-2,6-dicarboxylate anion, phen = 1,10-phenanthroline, dmphenH = 2,9-dimethyl-1,10-phenanthrolinium cation, 2,2'-bipyH = 2-(2-pyridyl)pyridinium cation, 4,4'-bipyH = 4-(4-pyridyl)pyridinium cation, have been prepared and characterized by the single-crystal X-ray structure analysis, infrared spectroscopy, and bymagnetic susceptibility and magnetization measurements. A zero field splitting was found in the Mn(III) dipicolinates while an antiferromagnetic exchange interaction was present in the Fe(III) dipicolinates.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganica chimica acta
ISSN
0020-1693
e-ISSN
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Volume of the periodical
425
Issue of the periodical within the volume
JAN
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
11
Pages from-to
134-144
UT code for WoS article
000345755700019
EID of the result in the Scopus database
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