Synthesis, crystal structure and magnetism of iron(III) and manganese(III) dipicolinates with pyridinemethanols

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F00216275%3A25310%2F14%3A39898442" target="_blank" >RIV/00216275:25310/14:39898442 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/14:00430152
Result on the web
<a href="http://dx.doi.org/10.1016/j.molstruc.2014.07.037" target="_blank" >http://dx.doi.org/10.1016/j.molstruc.2014.07.037</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2014.07.037" target="_blank" >10.1016/j.molstruc.2014.07.037</a>

Result language
angličtina
Original language name
Synthesis, crystal structure and magnetism of iron(III) and manganese(III) dipicolinates with pyridinemethanols
Original language description
Four ionic iron(III) and manganese(III) dipicolinato complexes of the formula (2-pymeH) [Fe-III(dipic)(2)]center dot[Fe-III(H2O)(2)Cl(dipic)center dot H2O, (3-pymeH)Mn-III(dipic)(2)]center dot 1.5H(2)O, (4-pymeH)[Fe-III(dipic)(2)]center dot 2H(2)O and (4-pymeH)[Mn-III(dipic)(2)]-2H(2)O, where H(2)dipic = pyridine-2,6-dicarboxylic acid, 2-pyme = 2-pyridinemethanol, 3-pyme = 3-pyridinemethanol, 4-pyme = 4-pyridinemethanol, have been prepared and characterized by the single-crystal X-ray structure analysis, infrared spectroscopy and magnetic measurements. The magnetic data were fitted to a zero-field splitting model revealing a slight magnetic anisotropy for Mn(III) systems. The molecular field correction was consistently formulated and included in the analysis for both, magnetic susceptibility and magnetization data.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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